1,2-Diphenyl-1H-benzimidazole

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1,2-Diphenyl-1H-benzimidazole

In the title mol-ecule, C19H14N2, the benzimidazole unit is close to being planar [maximum deviation = 0.0102 (6) Å] and forms dihedral angles of 55.80 (2) and 40.67 (3)° with the adjacent phenyl rings; the dihedral angle between the phenyl rings is 62.37 (3)°. In the crystal, one C-H⋯N hydrogen bond and three weak C-H⋯π inter-actions involving the fused benzene ring and the imidazole ring are ...

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1-Benzyl-1H-benzimidazole

In the title mol-ecule, C(14)H(12)N(2), the benzimidazole ring system is essentially planar (r.m.s. deviation = 0.024 Å). The dihedral angle between the imidazole ring and the benzyl ring is 85.77 (4)°. In the crystal, mol-ecules are linked into chains along the a axis by C-H⋯N hydrogen bonds. In addition, the packing is stabilized by C-H⋯π inter-actions involving both six-membered rings.

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2-Benzoyl-1H-benzimidazole

In the title compound, C(14)H(10)N(2)O, the benzoyl ring and benzimidazole ring system are aligned at a dihedral angle of 50.2 (2)°. In the crystal, inter-molecular N-H⋯N hydrogen bonds between adjacent imidazole groups generate supra-molecular C(4) chains running along the b axis.

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2-Trifluoro­methyl-1H-benzimidazole

The asymmetric unit of the title compound, C(8)H(5)F(3)N(2), consists of two half-mol-ecules, one lies on a mirror plane and the other is generated by twofold rotation symmetry, with the axis running through the trifluoro-methyl C atom and the attached benzimidazole C atom. The two 2-trifluoro-methyl-1H-benzimidazole mol-ecules are connected by N-H⋯N hydrogen bonds involving the disordered NH H...

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2-(3,4,5-Trimethoxy­phen­yl)-1H-benzimidazole

In the title compound, C(16)H(16)N(2)O(3), the dihedral angle between the mean planes of the aromatic ring systems is 30.90 (15)°. In the crystal structure, the mol-ecules form [010] chains by way of N-H⋯N hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812044960